Typical dose

0.5 mg to 5 mg taken 30-60 minutes before bedtim...

Oral Oral safety: very low

About this supplement

Immediate-release melatonin is the standard pharmaceutical formulation of the endogenous hormone N-acetyl-5-methoxytryptamine, designed for rapid dissolution and absorption following oral administration. Unlike extended-release forms, it delivers the entire dose quickly, producing a sharp peak in plasma concentration within 30-60 minutes to mimic the natural nocturnal rise of melatonin, thereby primarily signaling the onset of sleep. It is metabolized primarily in the liver via CYP1A2 enzymes and has a short half-life of approximately 20-50 minutes. This form is most commonly used for sleep onset difficulties and circadian rhythm phase shifts.

How much to take

Typical amount
0.5 mg to 5 mg taken 30-60 minutes before bedtime. Lower doses (0.5-1 mg) are often used for circadian phase shifting, while 3-5 mg is common for sleep initiation.
Suggested range
0.5 mg - 10 mg daily

Potential benefits

Benefits linked to this supplement form:

Things to watch for

Possible side effects linked to this form:

Health goals

Needs and goals this form may help with:

Other forms of Melatonin

Compare absorption and active amounts with sibling forms:

Technical details â–¼

Chemical ID (CAS)

73-31-4

Formula

C13H16N2O2

Physical properties

Typically a white to off-white crystalline powder. Practically insoluble in water, soluble in ethanol and DMSO. Melts at approximately 117°C.

How it’s made

Commercially produced almost exclusively via chemical synthesis. A common synthetic route involves the alkylation of 5-methoxyindole with a haloacetonitrile derivative, followed by hydrolysis and acetylation to form N-acetyl-5-methoxytryptamine. This process ensures high purity and consistency, free from biological contaminants.